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As the series progressed, Sam has learned to further develop his powers allowing him to exorcise demons from their human vessels and eventually to kill demons.
Sam has been shown to possess talents such as telekinesis and precognitive abilities (manifesting as visions).
Demon, Sam eventually reaches a point where no demon can harm him so long as he's high on demon blood.
To this end, Lilith is practically defenseless against Sam during their final confrontation.
Sam and Dean theorize that Sam only has premonitions when they are somehow related to the Yellow-Eyed Demon.
This is likely true, for Sam ceases to experience visions after the demon's death in 2.22 All Hell Breaks Loose: Part Two, which also suggests that his visions were a result of some sort of link between himself and YED.
Sam proves immune, and is later able to survive Lilith's "light" without any harm.
Killing a demon creates the same light inside their body as when they're killed by the Colt or Ruby's knife.
Initially they only occur when he's sleeping (through dreams), but by 1.14 Nightmare they occur when Sam is awake.
Sam cannot control when the premonitions occur or what they're about, and they are often accompanied by intense headaches.
In 11.23 Alpha and Omega, Lady Antonia Bevell has cork board with information on the family.
– Sam Winchester, 4.04 Metamorphosis Sam, and Dean's, middle name (if they have one) is unknown.
Unless the host is already dead, the vessel will survive this process (though he admitted to unintentionally killing a few during training).